In this paper, a high-performance Zinc-ion hybrid supercapacitor was fabricated using coal pitch derived porous carbon (CPC) as cathode material. The hierarchical porous structure of the CPC cathode material is conducive to the rapid diffusion of electrolyte, and the abundant nitrogen and oxygen doping can provide reaction sites for the chemical adsorption/desorption reaction of Li+ and Zn2+ for additional pseudocapacitive capacity. More importantly, the deposition/dissolution reversibility and stability of zinc anode can be improved using the optimized electrolyte adding lithium sulfate, and the ion diffusion rate can also be accelerated during the reaction process, thus improving the rate performance and cycle stability of the device.